Preparation of graphite intercalation compounds containing crown ethers. Using intercalation to simulate irradiation damage of. The aims of this work are to synthesize the hclo4 graphite intercalation compound gic by chemical method and analyze the effects of processing parameters on the exfoliated volume ev of hclo4. Motivated by recent experimental work, we use firstprinciples density functional theory methods to conduct an extensive search for low enthalpy structures of. What links here related changes upload file special pages permanent link page information wikidata item cite this page.
Intercalation compounds of graphite are of interest, both scienfically and technologically because of unusual properties that derive mainly from high degree of. Nomenclature and terminology of graphite intercalation compounds pdf. The synthesis of potassium gold graphite intercalation compounds has been performed. The graphite intercalation compounds and their applications. Pdf synthesis of intercalation compound of graphite and its. A sodiumethylenediamine graphite intercalation compound naethylenediaminec 15. The aims of this work are to synthesize the hclo4graphite intercalation compound gic by chemical method and analyze the effects of processing parameters on the exfoliated volume ev of hclo4. Superconductivity in graphite intercalation compounds. Diffusivity of lithium in a graphite intercalation. Graphite intercalation compounds gics for the first time are used as the anode material for lithium. Graphite intercalation compounds gics are often used to produce exfoliated or functionalised graphene related materials grms in a specific solvent.
Electronic supporting information files are available without a. Pdf layered graphene was prepared via the hydroxylation of potassium graphite intercalation compound kc 8 produced from exfoliated graphite flake. Pdf synthesis of intercalation compound of graphite and. Pdf evaluation of layered graphene prepared via hydroxylation. Experimental details, ex situ pxrd patterns, and gcms studies pdf. The electromagnetic absorption of a naethylenediamine. Files available from the acs website may be downloaded for personal. Overview on the intercalation of gold into graphite halcea.
Supplementary movie 2 is a more complete description of this experiment. Using intercalation to simulate irradiation damage of nuclear graphite lewis luyken 2012 a thesis submitted to the university of manchester for the. Gic and a new ternary system based on dimethylacetamide dmac. Not included are compounds with covalent bonding of heteroatoms to the carbon atoms which leads to a sp3 hybridization of the carbon atoms and a. Preparation of graphite intercalation compounds containing. Progression of fermi surfaces from pure graphite to stage1 intercalation. A new type of promising anode material for lithium. We report the first graphite intercalation compounds gics containing crown ethers. Pdf formation of gic graphite intercalation compound is an important field of study currently, as it offers a method of producing graphene by. Preparation of graphite intercalation compounds containing crown. Aqueous liion battery enabled by halogen conversion. Graphite intercalation compounds gics are complex materials having a formula cxm where.
Graphite is one material whose properties are quite remarkable. Diffusivity of lithium in a graphite intercalation compound by combination of transition state theory and first principles calculations kazuaki toyoura 1, yukinori koyama 1, akihide kuwabara 2 and isao tanaka1,2 1 department of materials science and engineering, kyoto university, kyoto 6068501, japan. The research on graphite intercalation compounds often acts as a forerunner for research in other sciences. Abstract graphite intercalation compounds gics are often used to produce exfoliated or functionalised graphene related materials grms in a specific solvent. Electrochemical intercalation of potassium into graphite. Gic made from graphite flakes was used to study the microwave absorption performance of a gic for the first time. Electrochemical intercalation of potassium into graphite jin zhao, xiaoxi zou, yujie zhu, yunhua xu, and chunsheng wang exceptional cycling performance of graphite anode in kion batteries is. Intercalation events visualized in single microcrystals of. They exhibit high reversible capacity with excellent cycle life. Media in category graphite intercalation compounds the following 6 files are in this category, out of 6 total. For instance, the concept of staging, which is fundamental to graphite intercalation compounds, is also relevant to surface science in connection with adsorbates on metal surfaces and to hightemperature superconducting oxide layer materials. Ion batteries wang 2014 advanced energy materials wiley.
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